Cost-effective iron-based aqueous redox flow batteries for large-scale ...
In 1974, L.H. Thaller a rechargeable flow battery model based on Fe 2+ /Fe 3+ and Cr 3+ /Cr 2+ redox couples, and based on this, the concept of "redox flow battery" was proposed for the first time [61]. The "Iron–Chromium system" has become the most widely studied electrochemical system in the early stage of RFB for energy storage.