Advanced silicon-based electrodes for high-energy lithium-ion …
For an understanding of the interest in silicon (Si) as an anode material for LIBs, consider the binary phase diagram for Li and Si shown in Fig. 11.1.Various stable compounds can be formed during the lithiation of silicon (Li 12 Si 7, Li 7 Si 3, Li 13 Si 4, and Li 22 Si 5).The corresponding redox potentials vs. Li + /Li are listed in Table 11.1.. Download: Download full …